Amc Ezee Trol 5b6d4r

AMC Ezee-Trol AMC

Chemwatch Hazard Alert Code: 1

Chemwatch: 23-2883

Issue Date: 01/01/2013

Version No: 4.1.1.1

Print Date: 10/16/2014

Safety Data Sheet according to WHS and ADG requirements

S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name

AMC Ezee-Trol

Chemical Name

Not Applicable

Synonyms

Ezee-Trol

Proper shipping name

Not Applicable

Chemical formula

Not Applicable

Other means of identification CAS number

Not Available Not Applicable

Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses

Drilling fluids compound, viscosifier, filtrate reducer.

Details of the manufacturer/importer AMC

AMC

216 Balcatta Rd Balcatta 6021 WA Australia

PO Box 1141 6916 WA Australia

Telephone

+61 8 9445 4000

+ 61 8 9445 4000

Fax

+61 8 9445 4040

+61 8 9445 4040

Website

www.amcoilandgas.com

Not Available

Email

[email protected]

Not Available

Not Available

Not Available

Emergency telephone numbers

1800 039 008 or +61 3 9573 3112,+800 2436 2255 +613 9573 3112

Not Available

Other emergency telephone numbers

1800 039 008 or +61 3 9573 3112,+800 2436 2255 +613 9573 3112

Not Available

ed company name Address

Emergency telephone number Association / Organisation

SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code. CHEMWATCH HAZARD RATINGS

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AMC Ezee-Trol Min

Flammability Toxicity Body Reactivity Chronic

Issue Date: 01/01/2013 Print Date: 10/16/2014

Max

1 0 0 1 0

0 = Minimum 1 = Low 2 = Moderate 3 = High 4 = Extreme

Poisons Schedule GHS Classification

[1]

Legend:

Not Applicable Acute Aquatic Hazard Category 3, Chronic Aquatic Hazard Category 3 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements GHS label elements

SIGNAL WORD

Not Applicable

NOT APPLICABLE

Hazard statement(s) H402

Harmful to aquatic life

H412

Harmful to aquatic life with long lasting effects

Precautionary statement(s): Prevention P273

Avoid release to the environment.

Precautionary statement(s): Response Not Applicable

Precautionary statement(s): Storage Not Applicable

Precautionary statement(s): Disposal P501

Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances Mixtures CAS No

%[weight]

Name

9004-32-4

>60

sodium carboxymethylcellulose

497-19-8

<5

AMC SODA ASH

533-74-4

<1

dazomet

cellulose filtration control agent, as

SECTION 4 FIRST AID MEASURES Description of first aid measures

Eye

Skin

Inhalation

Ingestion

If this product comes in with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair occurs: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If dust is inhaled, remove from contaminated area. Encourage patient to blow nose to ensure clear age of breathing. If irritation or discomfort persists seek medical attention. Immediately give a glass of water. First aid is not generally required. If in doubt, a Poisons Information Centre or a doctor.

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AMC Ezee-Trol

Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES Extinguishing media Water spray or fog.

Special hazards arising from the substrate or mixture Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Fire Incompatibility

Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard.

Fire Fighting

Solid which exhibits difficult combustion or is difficult to ignite.

Fire/Explosion Hazard

SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Clean up all spills immediately.

Minor Spills Major Spills

Moderate hazard. Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE Precautions for safe handling Avoid all personal , including inhalation.

Safe handling

Store in original containers.

Other information

Conditions for safe storage, including any incompatibilities Glass container is suitable for laboratory quantities Polyethylene or polypropylene container.

Suitable container Storage incompatibility

Cellulose and its derivatives may react vigorously with calcium oxide, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrate and sodium nitrite.

PACKAGE MATERIAL INCOMPATIBILITIES Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Not Available EMERGENCY LIMITS Ingredient

TEEL-0

TEEL-1

TEEL-2

TEEL-3

AMC Ezee-Trol

Not Available

Not Available

Not Available

Not Available

Ingredient

Original IDLH

Revised IDLH

sodium carboxymethylcellulose

Not Available

Not Available

AMC SODA ASH

Not Available

Not Available

dazomet

Not Available

Not Available

Exposure controls

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Issue Date: 01/01/2013 Print Date: 10/16/2014

AMC Ezee-Trol

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.

Personal protection

Eye and face protection Skin protection Hands/feet protection Body protection Other protection Thermal hazards

Safety glasses with side shields Chemical goggles. See Hand protection below The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. See Other protection below Overalls. Not Available

Recommended material(s)

Respiratory protection

GLOVE SELECTION INDEX Not Available AMC Ezee-Trol Material

I

NATURAL RUBBER

A

NITRILE

A

Not Available

Required Minimum Protection Factor

Half-Face Respirator

Full-Face Respirator

Powered Air Respirator

up to 10 x ES

P1 Air-line*

-

PAPR-P1 -

up to 50 x ES

Air-line**

P2

PAPR-P2

P3

-

Air-line*

-

Air-line**

PAPR-P3

up to 100 x ES 100+ x ES

-

* - Negative pressure demand ** - Continuous flow A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance

Light coloured odourless powder; soluble in water.

Physical state

Divided Solid

Relative density (Water = 1)

Odour

Not Available

Partition coefficient n-octanol / water

Not Available

Odour threshold

Not Available

Auto-ignition temperature (°C)

Not Available

pH (as supplied)

Not Available

Decomposition temperature

Not Available

Melting point / freezing point (°C)

165

1.5-1.6

Viscosity (cSt)

Not Applicable Not Applicable

Initial boiling point and boiling range (°C)

Not Available

Molecular weight (g/mol)

Flash point (°C)

Not Available

Taste

Not Available

Evaporation rate

Not Applicable

Explosive properties

Not Available

Flammability

Not Available

Oxidising properties

Not Available

Upper Explosive Limit (%)

Not Available

Surface Tension (dyn/cm or mN/m)

Not Applicable

Lower Explosive Limit (%)

Not Available

Volatile Component (%vol)

Not Available

Vapour pressure (kPa)

Not Applicable

Solubility in water (g/L)

Miscible

Vapour density (Air = 1)

Not Applicable

Gas group pH as a solution(1%)

Not Available 7.0-8.0

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AMC Ezee-Trol

Issue Date: 01/01/2013 Print Date: 10/16/2014

SECTION 10 STABILITY AND REACTIVITY Reactivity Chemical stability

See section 7 Unstable in the presence of incompatible materials.

Possibility of hazardous reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous decomposition products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Inhaled

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models).

Ingestion

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion".

Skin

The material is not thought to produce adverse health effects or skin irritation following (as classified by EC Directives using animal models).

Eye

Although the material is not thought to be an irritant (as classified by EC Directives), direct with the eye may cause transient discomfort characterised by tearing or conjunctival redness (as with windburn).

Chronic

Long term exposure to high dust concentrations may cause changes in lung function (i.e. pneumoconiosis) caused by particles less than 0.5 micron penetrating and remaining in the lung.

TOXICITY

IRRITATION

Not Available

Not Available

TOXICITY

IRRITATION

Oral (rat) LD50: 27000 mg/kg

Nil reported

Not Available

Not Available

TOXICITY

IRRITATION

Dermal (Rat) LD50: >2000 mg/kg *

Eye (rabbit): 100 mg/24h moderate

Inhalation (Guinea pig) LC50: 800 mg/m3/2h

Eye (rabbit): 100 mg/30s mild

Inhalation (Mouse) LC50: 1200 mg/m3/2h

Eye (rabbit): 50 mg SEVERE

Inhalation (rat) LC50: 2300 mg/m3/2h

Skin (rabbit): 500 mg/24h mild

AMC Ezee-Trol

sodium carboxymethylcellulose

AMC SODA ASH

Intraperitoneal (Mouse) LD50: 117 mg/kg Oral (Mouse) LD50: 6600 mg/kg Oral (Rat) LD50: 2800 mg/kg * Oral (rat) LD50: 4090 mg/kg Subcutaneous (Mouse) LD50: 2210 mg/kg

dazomet

Not Available

Not Available

TOXICITY

IRRITATION

Dermal (mouse) LD50: 2400 mg/kg

Eye (rabbit): 500 mg/24h - mild

Dermal (rabbit) LD50: 7000 mg/kg

Skin (rabbit): moderate

Dermal (rat) LD50: 2260 mg/kg

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AMC Ezee-Trol Inhalation (rat) LC50: 8400 mg/m3/4h Oral (guinea pig) LD50: 127 mg/kg Oral (mouse) LD50: 180 mg/kg Oral (mouse) LD50: 455 mg/kg (male) * Oral (mouse) LD50: 710 mg/kg (female) * Oral (rabbit) LD50: 120 mg/kg Oral (rat) LD50: 320 mg/kg Oral (rat) LD50: 520 mg/kg * Subcutaneous (mouse) LD50: 248 mg/kg Subcutaneous (rat) LD50: 470 mg/kg Not Available

Not Available

Not available.

SODIUM CARBOXYMETHYLCELLULOSE AMC SODA ASH

DAZOMET

Neoplastic by RTECS criteria

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. The following information refers to allergens as a group and may not be specific to this product. Oral (rabbit) LD50: 320-620 mg/kg * NOEL in rats 20 mg/kg diet. Toxicity Class WHO III; EPA III * Non-oncogenic * ADI: 0.0005 mg/kg/day

Acute Toxicity

Carcinogenicity

Skin Irritation/Corrosion

Reproductivity

Serious Eye Damage/Irritation

STOT - Single Exposure

Respiratory or Skin sensitisation

STOT - Repeated Exposure

Mutagenicity

Aspiration Hazard

CMR STATUS SECTION 12 ECOLOGICAL INFORMATION Toxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May be harmful to fauna if not disposed of according to Section 13 and legislative requirements. [AMC]

Persistence and degradability Ingredient

Persistence: Water/Soil

Persistence: Air

Not Available

HIGH

HIGH

Not Available

LOW

LOW

Bioaccumulative potential Ingredient

Bioaccumulation

Not Available

LOW (BCF = 3.162)

Not Available

LOW (BCF = 2.388)

Mobility in soil Ingredient

Mobility

Not Available

HIGH (KOC = 1)

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AMC Ezee-Trol

Not Available

LOW (KOC = 13.64)

SECTION 13 DISPOSAL CONSIDERATIONS Waste treatment methods Product / Packaging disposal

Legislation addressing waste disposal requirements may differ by country, state and/ or territory.

SECTION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant: NO HAZCHEM

Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Inland waterways transport (ADNR / River Rhine): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS UN number

Not Available

Packing group

Not Available

UN proper shipping name

Not Available

Environmental hazard

No relevant data Not Available

Transport hazard class(es)

Not Applicable

Classification code

Not Available

Limited quantity

Not Available

Equipment required

Not Available

Fire cones number

Not Available

Special precautions for

Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC code Source

Ingredient

Pollution Category

Residual Concentration - Outside Special Area (% w/w)

Residual Concentration

IMO MARPOL 73/78 (Annex II) List of Noxious Liquid Substances Carried in Bulk

AMC SODA ASH

Z

Not Available

Not Available

SECTION 15 REGULATORY INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture sodium carboxymethylcellulose(9004-32-4) is found on the following regulatory lists

"Australia Inventory of Chemical Substances (AICS)"

AMC SODA ASH(497-19-8) is found on the following regulatory lists

"Australia Inventory of Chemical Substances (AICS)","Australia Hazardous Substances Information System Consolidated Lists"

dazomet(533-74-4) is found on the following regulatory lists

"Australia Inventory of Chemical Substances (AICS)","Australia Hazardous Substances Information System Consolidated Lists"

SECTION 16 OTHER INFORMATION Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards

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AMC Ezee-Trol

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are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.