Knife Line Attack Compiled and edited by Nasrizal Mohd Rashdi Senior Lecturer Fabrication & ing Section Universiti Kuala Lumpur
Knife Line Attack Occur
in stabilized austenitic stainless steel such as 321 & 347. It also inter-granular corrosion but not same as weld decay. Also cause by precipitation of Chromium carbide at grain boundary.
Differs from weld decay Occurs
in narrow band in the area immediately adjacent to weld metal. Occurs in stabilized SS
Mechanism The
area corresponding to thermal cycle ‘1’ is very close to the fusion boundary Therefore is subjected to both a very high peak temperature and a very rapid cooling rate during welding. This peak temperature is above the solvus temperature of titanium carbide, so it will dissolves in this area.
Mechanism
Because of the rapid cooling rate through its precipitation temperature range, titanium carbide does not re-precipitate during cooling Thus leaving abundant free carbon atoms in this area. When the weld is reheated in the Cr carbide precipitation range (for stress-relief or in multiple- welding), Ti carbide does not form appreciably since the temperature level is not high enough.
Consequently,
Cr carbide precipitates at grain boundaries, and this area becomes susceptible to intergranular corrosion attack.
Because
of the high temperate gradient near the fusion boundary and the high Ti carbide dissolution temperature, the region in which Ti carbide dissolves during welding is very narrow
As
a result, subsequent intergranular corrosion attack occurs in a very narrow strip immediately adjacent to the fusion boundary, and thus the name knife-line attack. Figure 18.15 shows the transmission electron
Prevention methods Addition
It reduce the rate of intergranular corrosion. (see fig. 18-18). It no adverse effects on mechanical properties.
Post
of rare earth metal ( La + Ce).
weld heat treatment.
Heat to 1000OC to 1100OC, to dissolving the chromium carbide and than rapid quenching.
Use
low carbon grade.
Question State
the area are possibility to knife line attack
First
second